Investigation of thermal conductivity property of plasmonic nanofluids based on gold nanorods prepared by seed-mediated growth method
Mahsa Mohammadzadeh
Mohsen Ashjari
Davoud Zare
Abstrakt
In this paper, nanofluids were prepared based on gold nanorods in basic fluid, water, by single-stage chemical reduction and in different volume fractions and the used gold nanorods were synthesized by seed-mediated growth method in different dimensional ratios. The properties of the prepared nanoparticles, including crystalline size, aspect ratio, surface properties, nanoparticle purity, shape and morphology of nanostructures were investigated using x-ray diffraction, UV-vis spectroscopy, FT-IR, and transmitted electron microscopy. The effect of changing parameters of Nano rod dimensions, changes in Nano rod volume fraction in water and also the effect of temperature on the nanofluid thermal conductivity coefficient were investigated using transient hot wire method. The results showed that reducing the aspect ratio, increasing the volume fraction and increasing the temperature increase the thermal conductivity. In fact, results show that an increase in the nanorods aspect ratio with a constant volume fraction of 1:50 of gold in water nanorod and at room temperature leads to a decrease in the thermal conductivity of the nanofluid. Also, increasing the two parameters of volume fraction and temperature significantly increases the thermal conductivity coefficient.
Słowa kluczowe:
nanofluid, gold nanorod, thermal conductivity, transient hot wire method, aspect ratio, volume fractionBibliografia
Bohren C.F., Huffman D.R. 2007. Absorption and Scattering of Light by Small Particle. WILEY-VCH, Hoboken, New Jersey, USA. Google Scholar
Burda C., Chen X., Narayanan R., El-Sayed M.A. 2005. Chemistry and properties of nanocrystals of different shapes. Chemical Reviews, 105(4): 1025-1102. Google Scholar
Choi S.U.S., Eastman J.A. 1995. Enhancing thermal conductivity of fluids with nanoparticles. American Society of Mechanical Engineers (ASME), 66: 99-105. Google Scholar
Chopkar M., Sudarshan S., Das P.K., Manna I. 2008. Effect of Particle Size on Thermal Conductivity of Nanofluid. Metallurgical and Materials Transactions A, 39(7): 1535-1542. Google Scholar
Decagon, USA; http://issuu.com//decaweb/docs/kd2man. Google Scholar
Draine B.T., Flatau P.J. 1994. Discrete-dipole approximation for scattering calculations. Journal of the Optical Society of America, 11(4): 1491–1499. Google Scholar
Eastman J.A., Choi S.U.S., Li S., Yu W., Thompson L.J. 2001. Anomalously increased effective thermal conductivities of ethylene glycol-based nanofluids containing copper nanoparticles. Applied Physics Letters, 78(6): 718-720. Google Scholar
Gentili D., Ori G., Franchini M.C. 2009. Double phase transfer of gold nanorods for surface functionalization and entrapment into PEG-based nanocarriers. Chemical Communications, 39: 5874-5876. Google Scholar
Govorov A.O., Zhang W., Skeini T., Richardson H., Lee J., Kotov N.A. 2006. Gold nanoparticle ensembles asheaters and actuators: melting and collective plasmon resonances. Nanoscale Research Letters, 1(1): 84–90. Google Scholar
Hutter E., Fendler J.H. 2004. Exploitation of localized surface plasmon resonance. Advanced Materials, 16(19): 1685–1706. Google Scholar
Jain P.K., Lee K.S., El-Sayed I.H., El-Sayed M.A. 2006. Calculated absorption and scattering properties of gold nanoparticles of different size, shape and composition: applications in biological imaging and biomedicine. The Journal of Physical Chemistry, 110(14): 7238–7248. Google Scholar
Jain S., Hirst D.G., O’sullivan J.M. 2012. Gold nanoparticles as novel agents for cancer therapy. The British Journal of Radiology, 85(1010): 101-113. Google Scholar
Jana N.R., Gearheart L., Murphy C.J. 2001. Seed-Mediated Growth Approach for Shape-Controlled Synthesis of Spheroidal and Rod-Like Gold Nanoparticles Using a Surfactant Template. Advanced Materials, 13(18): 1389−1393. Google Scholar
Jana N.R., Gearheart L., Murphy C.J. 2001. Wet Chemical Synthesis of High Aspect Ratio Cylindrical Gold Nanorods. The Journal of Physical Chemistry, 105(19): 4065−4067. Google Scholar
Jha N., Ramprabhu S. 2009. Thermal conductivity studies of metal dispersed multiwalled carbon nanotubes in water and ethylene glycol based nanofluids. Journal of Applied Physics, 106(8): 084317. Google Scholar
Jia Y., Sun T.Y., Wang J.H., Huang H., Li P.H., Yu X.F., Chu P.K. 2014. Synthesis of hollow rare-earth compound nanoparticles by a universal sacrificial template method. CrystEngComm, 16(27) 6141–6148. Google Scholar
Karthikeyan N.R., Philip J., Raj B. 2008. Effect of clustering on the thermal conductivity of nanofluids. Materials Chemistry and Physics, 109(1): 50-55. Google Scholar
Khullar V., Tyagi H., Phelan P.E., Otanicar T.P., Singh H., Taylor R.A. 2012. Solar Energy Harvesting Using Nanofluids-Based Concentrating Solar Collector. Journal of Nanotechnology in Engineering and Medicine, 3(3): 259-267. Google Scholar
Lee B.J., Park K., Walsh T., Xu L. 2012. Radiative Heat Transfer Analysis in Plasmonic Nanofluids for Direct Solar Thermal Absorption. Journal of Solar Energy Engineering, 134(2): 021009. Google Scholar
Lei W., Mochalin V., Liu D., Qin S., Gogotsi Y., Chen Y. 2015. Boron nitride colloidal solutions, ultralight aerogels and freestanding membranes through one-step exfoliation and functionalization. Nature Communications, 6(1): 8849. Google Scholar
Li Q., Xuan Y., Wang J. 2005. Experimental investigations on transport properties of magnetic fluids. Experimental Thermal and Fluid Science, 30(2): 109-116. Google Scholar
Li Y., Zhou J., Tung S., Schneider E., Xi S. 2009. A review on development of nanofluid preparation and characterization. Powder Technology, 196(2): 89-101. Google Scholar
Link S., El-Sayed M.A. 1999. Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nanodots and nanorods. The Journal of Physical Chemistry, 103(40): 8410–8426. Google Scholar
Lo C.H., Tsung T.T., Lin H.M. 2007. Preparation of silver nanofluid by the submerged arc nanoparticle synthesis system (SANSS). Journal of Alloys and Compounds, 434-435: 659-662. Google Scholar
Mohammadi A., Kaminski F., Sandoghdar V., Agio M. 2009. Spheroidal nanoparticles as nanoantennas for fluorescence enhancement. International Journal of Nanotechnology, 6(10-11): 902–914. Google Scholar
Murshed S.M.S., Leong K.C., Yang C. 2008. Thermophysical and electrokinetic properties of nanofluids – a critical review. Applied Thermal Engineering, 28(17-18): 2109-2125. Google Scholar
Nikoobakht B., El-Sayed M.A. 2003. Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method. Chemistry of Materials, 15(10): 1957−1962. Google Scholar
Palik E. 1998. Handbook of optical constants of solids. 1st Edition. Academic Press, London. Google Scholar
Patel H.E., Sundararajan T., Das S.K. 2008. A cell model approach for thermal conductivity of nanofluids. Journal of Nanoparticle Research, 10(1): 87–97. Google Scholar
Paul G., Philip J., Raj B., Kumar-Das P., Manna I. 2011. Synthesis, characterization, and thermal property measurement of nano-Al95Zn05 dispersed nanofluid prepared by a two-step process. International Journal of Heat and Mass Transfer, 54(15-16): 3783-3788. Google Scholar
Prasher R., Bhattacharya P., Phelan P.E. 2006. Brownian-motion-based convective-conductive model for the effective thermal conductivity of nanofluids. Journal of Heat Transfer, 128(6): 588-595. Google Scholar
Raether H. 1988. Surface Plasmons on Smooth and Rough Surfaces and on Gratings. Springer-Verlag. Google Scholar
Richardson H.H., Hickman Z.N., Govorov A.O., Thomas A.C., Zhang W., Kordesch M.E. 2006. Thermooptical Properties of Gold Nanoparticles Embedded in Ice: Characterization of Heat Generation and Melting. Nano Letters, 6(4): 783–788. Google Scholar
Sani E., Barison S., Pagura C., Mercatelli L., Sansoni P., Fontani D., Jafrancesco D., Francini F. 2010. Carbon nanohorns-based nanofluids as direct sunlight absorbers. Optics Express, 18(5): 5179–5787. Google Scholar
Sani E., Mercatelli L., Barison S., Pagura C., Agresti F., Colla L., Sansoni P. 2011. Potential of carbon nanohorn-based suspensions for solar thermal collectors. Solar Energy Materials and Solar Cells, 95(11): 2994–3000. Google Scholar
Suresh S., Venkitaraj K.P., Selvakumar P., Chandrasekar M. 2011. Synthesis of Al2O3–Cu/ water hybrid nanofluids using two step method and its thermo physical properties. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 388(1-3): 41-48. Google Scholar
Taha-Tijerina J., Narayanan T.N., Gao G., Rohde M., Tsentalovich D.A., Pasquali M., Ajayan P.M. 2012. Electrically Insulating Thermal Nano-Oils Using 2D Fillers. ACS Nano, 6(2): 1214-1220. Google Scholar
Takahashi H., Niidome T., Kawano T., Yamada S., Niidome Y. 2008. Surface modification of gold nanorods using layer-by-layer technique for cellular uptake. Journal of Nanoparticle Research, 10(1): 221-228. Google Scholar
Taylor R.A., Otanicar T.P., Herukerrupu Y., Bremond F., Rosengarten G., Hawkes E.R., Jian X., Coulombe S. 2013. Feasibility of nanofluid-based optical filters. Applied Optics, 52(7): 1413–1422. Google Scholar
Tillman P., Hill J.M. 2006. A new model for thermal conductivity in nanofluids. Proceeding of 2006 International Conference on Nanoscience and Nanotechnology. Eds. C. Jagadish, G. Lu. Canberra, Australia, p. 673-676. Google Scholar
Tseng K.H., Lee H.L., Liao C.Y., Chen K.C., Lin H.S. 2013. Rapid and Efficient Synthesis of Silver Nanofluid Using Electrical Discharge Machining. Journal of Nanomaterials, 2013: 6-12. Google Scholar
Tyagi H., Phelan P., Prasher R. 2009. Predicted Efficiency of a Low-Temperature Nanofluid-Based Direct Absorption Solar Collector. Journal of Solar Energy Engineering, 131(4): 041004. Google Scholar
Wang L.P., Lee B.J., Wang X.J., Zhang Z.M. 2009. Spatial and temporal coherence of thermal radiation in asymmetric Fabry-Perot resonance cavities. International Journal of Heat and Mass Transfer, 52(13-14): 3024–3031. Google Scholar
Wang Q., Fu F. 2011. Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management, 92(3): 407-418. Google Scholar
Xie H., Fujii M., Zhang X. 2005. Effect of interfacial nanolayer on the effective thermal conductivity of nanoparticle-fluid mixture. International Journal of Heat and Mass Transfer, 48(14): 2926-2932. Google Scholar
Yan K.Y., Xue Q.Z., Zheng Q.B., Hao L.Z. 2007. The interface effect of the effective electrical conductivity of carbon nanotube composites. Nanotechnology, 18(25): 255705. Google Scholar
Yu W., Choi S.U.S. 2003. The Role of Interfacial Layers in the Enhanced Thermal Conductivity of Nanofluids: A Renovated Maxwell Model. Journal of Nanoparticle Research, 5(1-2): 167-171. Google Scholar
Yu W., Choi S.U.S. 2004. The role of interfacial layers in the enhanced thermal conductivity of nanofluids: A renovated Hamilton – Crosser model. Journal of Nanoparticle Research, 6(4): 355-361. Google Scholar
Yu W., Xie H. 2012. A Review on Nanofluids: Preparation, Stability Mechanisms, and Applications. Journal of Nanomaterials, 2012: 17-34. Google Scholar
Zayats A.V., Smolyaninov I.I., Maradudin A.A. 2005. Nano-optics of surface plasmon polaritons. Physics Reports, 408(3-4): 131–314. Google Scholar
Zhang F., Shi Y.F., Sun X.H., Zhao D.Y., Stucky G.D. 2009. Formation of hollow upconversion rare-earth fluoride nanospheres: Nanoscale Kirkendall effect during ion exchange. Chemistry of Materials, 21(21): 5237–5243. Google Scholar
